Energies, Vol. 19, Pages 99: A Combined FEM-CFD Method for Investigating Transport Properties of Compressed Porous Electrodes in PEMFC: A Microstructure Perspective

Energies, Vol. 19, Pages 99: A Combined FEM-CFD Method for Investigating Transport Properties of Compressed Porous Electrodes in PEMFC: A Microstructure Perspective

Energies doi: 10.3390/en19010099

Authors:
Zhuo Zhang
Ruiyuan Zhang
Xiuli Zhang
Zhiyi Tang
Zixing Wang
Yang Wang
Yanjun Dai
Li Chen
Wenquan Tao

Hydrogen energy is vital for a clean, low-carbon society, and proton exchange membrane fuel cells (PEMFCs) represent a core technology for the conversion of hydrogen chemical energy into electrical energy. When PEMFC single cells are stacked under assembly force for high power output, their porous electrodes (gas diffusion layers, GDLs; catalyst layers, CLs) undergo compressive deformation, altering internal transport processes and affecting cell performance. However, existing microscale studies on PEMFC porous electrodes insufficiently consider compression (especially in CLs) and have limitations in obtaining compressed microstructures. This study proposes a combined framework from a microstructure perspective. It integrates the finite element method (FEM) with computational fluid dynamics (CFD). It reconstructs microstructures of GDL, CL, and GDL-bipolar plate (BP) interface. FEM simulates elastic compressive deformation, and CFD calculates transport properties (solid zone: heat/charge conduction via Laplace equation; fluid zone: gas diffusion/liquid permeation via Fick’s/Darcy’s law). Validation shows simulated stress–strain curves and transport coefficients match experimental data. Under 2.5 MPa, GDL’s gas diffusivity drops 16.5%, permeability 58.8%, while conductivity rises 2.9-fold; CL compaction increases gas resistance but facilitates electron/proton conduction. This framework effectively investigates compression-induced transport property changes in PEMFC porous electrodes.