Unstable Slip in Fault Gouge Driven by Temperature and Water

arXiv:2603.16921v1 Announce Type: new
Abstract: Microscale granular sliding within fault gouge is fundamental to earthquake nucleation, yet the mechanism by which temperature affects friction through interfacial water remains poorly understood. Here, large-scale molecular dynamics simulations were conducted on a hydrophilic quartz-water-quartz interface over 300-500 K to quantify temperature-dependent changes in frictional strength, real contact area, and water-layer structure. Results show that both the friction coefficient and friction force decrease monotonically with increasing temperature, following near-linear relationships of $mu propto T^{-1}$ and $F_t propto A$, indicating that frictional weakening is primarily governed by temperature-driven contact restructuring. Structural analyses further show that heating progressively disrupts the hydrogen-bond network in the first adsorption layer, reduces adsorption-layer density, and weakens radial distribution peaks, demonstrating a transition of interfacial water from an ordered, strongly adsorbed state to a more diffuse, weakly bound configuration with delayering and quasi-phase-transition behavior. This interfacial reconstruction weakens intergranular bridging and structural cohesion, promoting a shift from structural locking to water-mediated lubrication. These results suggest that frictional stability under coupled temperature-water conditions is strongly controlled by the thermal evolution of interfacial water structure.