Partial Molar Volumes in Highly Siliceous Melts and the Relationship to Liquid Immiscibility
Non-ideal mixing in binary melts (Li₂O-SiO₂, Na₂O-SiO₂, K₂O-SiO₂, BaO-SiO₂) causes volume changes; the non-ideal mixing constant (Vₓ) increases with the degree of non-ideality.
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