Energies, Vol. 18, Pages 4181: Synergy of Fly Ash and Surfactant on Stabilizing CO2/N2 Foam for CCUS in Energy Applications
Energies doi: 10.3390/en18154181
Authors:
Jabir Dubaish Raib
Fujian Zhou
Tianbo Liang
Anas A. Ahmed
Shuai Yuan
The stability of nitrogen gas foam hinders its applicability in petroleum applications. Fly ash nanoparticles and clay improve the N2 foam stability, and flue gas foams provide a cost-effective solution for carbon capture, utilization, and storage (CCUS). This study examines the stability, volume, and bubble structure of foams formed using two anionic surfactants, sodium dodecyl sulfate (SDS) and sodium dodecylbenzene sulfonate (SDBS), along with the cationic surfactant cetyltrimethylammonium bromide (CTAB), selected for their comparable interfacial tension properties. Analysis of foam stability and volume and bubble structure was conducted under different CO2/N2 mixtures, with half-life and initial foam volume serving as the evaluation criteria. The impact of fly ash and clay on SDS-N2 foam was also evaluated. The results showed that foams created with CTAB, SDBS, and SDS exhibit the greatest stability in pure nitrogen, attributed to low solubility in water and limited gas diffusion. SDS showed the highest foam strength attributable to its comparatively low surface tension. The addition of fly ash and clay significantly improved foam stability by migrating to the gas–liquid interface, creating a protective barrier that reduced drainage. Both nano fly ash and clay improved the half-life of nitrogen foam by 11.25 times and increased the foam volume, with optimal concentrations identified as 5.0 wt% for fly ash and 3.0 wt% for clay. This research emphasizes the importance of fly ash nanoparticles in stabilizing foams, therefore optimizing a foam system for enhanced oil recovery (EOR).