Energies, Vol. 18, Pages 5868: Numerical Modeling and Multiscale Evaluation of Fe3O4–Graphene Oxide Nanofluids in Electromagnetic Heating for Colombian Heavy Oil Recovery

Energies, Vol. 18, Pages 5868: Numerical Modeling and Multiscale Evaluation of Fe3O4–Graphene Oxide Nanofluids in Electromagnetic Heating for Colombian Heavy Oil Recovery

Energies doi: 10.3390/en18225868

Authors:
Paola A. León
Andres F. Ortíz
Jimena Gómez-Delgado
Daniela Barrera
Fabian Tapias
Nicolas Santos
Enrique Mejía-Ospino

Electromagnetic heating (EMH) using microwaves has emerged as a promising enhanced oil recovery (EOR) technique, particularly for heavy crude oils where conventional thermal methods encounter technical and environmental challenges. However, its large-scale implementation remains limited due to incomplete understanding of its energy transfer mechanisms. This study proposes an experimental–numerical approach integrating magnetic graphene oxide nanoparticles (Fe3O4@GO) with microwave heating to enhance energy absorption near the wellbore. The nanomaterial was synthesized via a modified Hummer’s method followed by in situ magnetite precipitation and studied through multiple material characterization techniques showing uniform 80 nm particles with superparamagnetic behavior—ideal for EMH applications. Nine experiments were conducted on sand–heavy-oil–water systems with nanoparticle concentrations up to 500 ppm using a laboratory microwave heating prototype. A simulation model was then developed in CMG-STARS for history matching to estimate energy absorption as a function of saturation and nanoparticle concentration. Experiments reached temperatures up to 240 °C, with 653 MJ of effective heat transferred to the target zone over 55 h, as estimated from the input heat required in the simulator for history matching. The results confirm that magnetic graphene oxide nanoparticles enhance thermal efficiency and heat distribution in microwave-assisted EOR.