arXiv:2512.22157v1 Announce Type: new
Abstract: This paper presents a matrix-based exchange factor transformation for solving coupled mixed boundary condition radiative transfer problems on general domains. The method applies to participating media ranging from transparent to absorbing, emitting, and scattering, with boundaries ranging from absorbing to reflecting. Given a first-interaction exchange factor matrix $mathbf{F}$, the transformation produces an absorption matrix $mathbf{A}$ and a multiple reflection-scattering matrix $mathbf{R}$ through a Neumann series that analytically traces all reflection-scattering paths to steady state. The paper establishes rigorous conditions under which the method guarantees convergence, non-negative radiation, and exact energy conservation to machine precision. A comparison with Noble’s matrix formulation of Hottel’s zonal method reveals a previously unidentified discrepancy in that classical approach; the proposed transformation eliminates this discrepancy. The method is validated against the diffusion approximation in the high-extinction limit and against results of Crosbie and Schrenker for pure and partial scattering cases. The method is applicable to medium-scale general reflecting-scattering problems and scales to large problems when negligible reflection-scattering and high extinction ensure matrix sparsity.