Energies, Vol. 19, Pages 1108: From Invasive Alien Species to Resource: Hydrothermal Carbonization of Myriophyllum aquaticum
Energies doi: 10.3390/en19041108
Authors:
Federica Barontini
Marco Landi
Nicola Silvestri
Sandra Vitolo
Monica Puccini
The invasive aquatic plant Myriophyllum aquaticum represents both an ecological threat and a wet biomass disposal challenge. This study investigates hydrothermal carbonization (HTC) as a strategy for its valorisation into energy-dense hydrochar. A Design of Experiments–Response Surface Methodology (DoE-RSM) approach was applied to elucidate the combined influence of temperature (200–260 °C), residence time (30–210 min), and solid load (5–25 wt%) on hydrochar yield and properties. Hydrochar yields ranged from 48.8% to 65.6%, with the highest yields achieved at 200 °C, 30 min, and 25 wt% solids. Higher heating values of hydrochars spanned from 12.14 to 14.53 MJ/kg, corresponding up to +19% energy densification at higher process severity. Carbon and energy yields reached 69.7% and 68.6%, respectively, with maximum values attained under low-severity, high-solid-load conditions. The predictive models exhibited strong agreement with experimental data, enabling optimisation of HTC parameters for targeted hydrochar applications. Two hydrochars, “peat-like” and “lignite-like”, were further characterised for their potential use as soil amendments. The lignite-like hydrochar complied with EU contaminant limits and showed no phytotoxicity, confirming its suitability for agronomic use. Overall, HTC of M. aquaticum provides an effective waste-to-resource pathway, transforming wet invasive biomass into value-added carbon materials.