Energies, Vol. 19, Pages 1504: Effect of Graphene Nanoplatelet Size on the Thermal Properties of Bio-Based Phase-Change Materials for Thermal Energy Storage
Energies doi: 10.3390/en19061504
Authors:
Elisangela Jesus D’Oliveira
Yolanda Sanchez-Vicente
Saeid Mehvari
Sol Carolina Costa Pereira
The rising environmental impact of building energy consumption has intensified the demand for sustainable energy solutions. Latent heat thermal energy storage (LHTES) using phase-change materials (PCMs) offers a highly effective approach to improve energy efficiency; however, the intrinsically low thermal conductivity of most PCMs limits their practical performance. This study explores the thermophysical properties of a commercially available bio-based PCM (CrodaThermTM 60) enhanced with graphene nanoplatelets (GNPs) to improve heat transfer performance. Nano-enhanced PCMs (NePCMs) were prepared using a two-step process combining magnetic stirring and ultrasonication, incorporating GNPs at 2, 4, and 6 wt.%. Solid-phase density measurements of the NePCMs and viscosity measurements of the pure PCM were also conducted to support material characterisation. The results indicate distinct behaviours for the two nanoparticle sizes. At 6 wt.% nanoparticle loading, for 2 nm particles, the thermal conductivity increases by up to 13.9%, whereas for 6–8 nm particles, the enhancement is 148.9% of the pure PCM. Additionally, a reduction in latent heat is observed, with a proportional relationship to mass loading, as expected. These findings underscore the need for improved nanoparticle dispersion and formulation strategies to optimise both thermal performance and stability.